ABSTRACT This study evaluated leaf supply of zinc (Zn) and boron (B) using either soluble or sparingly soluble fertilizers in young sweet orange trees. Three experiments were set up in a greenhouse to compare two sources and four doses (control, low, adequate and high) of fertilizers as follows: (i) Experiment I (B): boric acid and calcium borate; (ii) Experiment II (Zn): Zn sulfate and Zn oxide; and (iii) Experiment III (B + Zn): boric acid + Zn Sulfate and Zn Borate. The sparingly soluble sources were effective in increasing the Zn and B leaf concentration. Dry matter of the aerial part increased 18 % with B applications in adequate concentration independent of the B fertilizer sources. In contrast, trees did not grow well with applications of adequate concentration of Zn as Zn Sulfate or high Zn concentration as Zn borate. Superoxide dismutase activity in leaves increased with applications of low concentration of Zn as Zn oxide and decreased with high concentration of Zn from either source. Polyphenol oxidase activity increased with application of adequate concentration of B as boric acid and high concentration of B as calcium borate. Furthermore, the upper concentrations of Zn were toxic in orange trees when the source was Zn sulfate. Increases in plant growth without damage to leaf tissue and positive responses of key enzymes of orange trees in a range of nutrient concentration applications demonstrated the practical use of sparingly soluble fertilizers to supplying B and Zn foliarily to plants.

ABSTRACT Deficiencies of boron and zinc occur in coffee plantations despite the many fertilizer sources offered by the industry for the agriculture. Sparingly soluble fertilizers (SSF) have been used in several countries for many years. However, their effectiveness when applied to leaves is highly contested, and information about their use efficiency is still lacking. Experiments were set up to characterize the SSF of B and Zn according to particle size of fertilizers, and the spreading and retention of the particles in the leaf, comparing SSF (calcium borate, Zn oxide, and Zn borate) with soluble sources (boric acid and Zn sulfate) in four doses (mg.L-1): Experiment I (B 0, 130, 260, and 520), Experiment II (Zn 0, 200, 600, and 1,800), and experiment III (B 0, 43, 129, and 387, and Zn 0, 200, 600, and 1,800), to supply B and Zn for coffee plants. Microparticles of the SSF were found adhered to coffee leaves, and the Zn oxide was the one with the smallest particle size. SSFs were effective at increasing the Zn and B leaf concentrations in coffee. Dry matter of coffee increased 15% with applications of 270 mg.L-1 of B as calcium borate and 384 mg.L-1 of B as boric acid. Foliar application of Zn oxide at the dose of 1,800 mg.L-1 of Zn increased the leaf areas of the plants. High doses of Zn sulfate caused toxicity to coffee plants due to high saline concentrations. The microparticles found retained on the surface of the coffee leaves increased leaf concentration of B and Zn, which explained variations in the dry matter measurements and show the potential of the SSF for the development of fertilizers to improve the availability of micronutrients to coffee.